Yup. Cap is "The peak of human ability" according to just about everything relating to the effects of the serum. Spidey has the "proportial strength of a spider", which delves into a lot of mass and density talk that makes my head hurt, but he's been shown lifting 20 tons as recently as the last 10 years.
Plus during the Secret Invasion, Spider Man knocked out a Tyranosaurus Rex with one punch. He wins.